Synthesis and optical resolution of a Cu(I) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands.

نویسندگان

  • Yoshio Furusho
  • Hidetoshi Goto
  • Ken Itomi
  • Hiroshi Katagiri
  • Toyoharu Miyagawa
  • Eiji Yashima
چکیده

A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF(6) without racemization.

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عنوان ژورنال:
  • Chemical communications

دوره 47 35  شماره 

صفحات  -

تاریخ انتشار 2011